Do paramagnetic platinum metal hydrides really exist? A reinvestigation of the synthesis and magnetochemical properties of Ir(H)x(Cl)2(P-i-Pr3)2 (1). Syntheses and crystal structure determinations of trans-Ir(H)(Cl)2(CO)(P-i-Pr3)2 (2), cis-Ir(H)(Cl)2(CO)(P-i-Pr3)2 (4) and trans-Ir(Cl)(CO)(P-i-Pr3)2 (5)-Reference-Cited by-同舟云学术

Do paramagnetic platinum metal hydrides really exist? A reinvestigation of the synthesis and magnetochemical properties of Ir(H)x(Cl)2(P-i-Pr3)2 (1). Syntheses and crystal structure determinations of trans-Ir(H)(Cl)2(CO)(P-i-Pr3)2 (2), cis-Ir(H)(Cl)2(CO)(P-i-Pr3)2 (4) and trans-Ir(Cl)(CO)(P-i-Pr3)2 (5)

Published:1997-05 Issue:2 Volume:258 Page:169-181
ISSN:0020-1693
Container-title:Inorganica Chimica Acta
language:en
Short-container-title:Inorganica Chimica Acta

Author:

Capitani Donatella,Mura Pasquale

Publisher

Elsevier BV

Subject

Materials Chemistry,Inorganic Chemistry,Physical and Theoretical Chemistry

Reference28 articles.

1. Synthesis and x-ray crystal structure of the stable paramagnetic iridium dihydrido complex Ir(H)2(Cl)2(P-iso-Pr3)2

2. Unusual Behavior of the Stable Paramagnetic Dihydridoiridium(IV) Complex[Ir(H)2(Cl)2(iPr3P)2] in Solution

3. Stable paramagnetic dihydrido complexes of iridium(IV): synthesis, x-ray crystal structure, and behavior in solution of IrIV(H)2(Cl)2(P-iso-Pr3)2 (1) and IrIV(H)2(Cl)2(PCy3)2 (2)

4. Photochemical reactivity of 2[IrIIIHCl2(PPri3)2]·H2. Formation of monohydrido isomers of IrIIIand evidence of photoinduced oxidative addition of H2, to IrIII

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