Solution studies of N′,N″,N″′-tris(3-aminopropyl)amine-based zinc(II) complexes and X-ray crystal structures of [Zn(trpn)](ClO4)2 and [Zn(trpn)(DETP)]ClO4, DETP−=O,O-diethyl thiophospate. Catalytic activity of the complexes in the hydrolysis of the phosphotriester 2,4-dinitrophenyl diethyl phosphate-Reference-Cited by-同舟云学术

Solution studies of N′,N″,N″′-tris(3-aminopropyl)amine-based zinc(II) complexes and X-ray crystal structures of [Zn(trpn)](ClO4)2 and [Zn(trpn)(DETP)]ClO4, DETP−=O,O-diethyl thiophospate. Catalytic activity of the complexes in the hydrolysis of the phosphotriester 2,4-dinitrophenyl diethyl phosphate

Published:2003-09 Issue: Volume:353 Page:187-196
ISSN:0020-1693
Container-title:Inorganica Chimica Acta
language:en
Short-container-title:Inorganica Chimica Acta

Author:

Ibrahim M.M,Ichikawa Kazuhiko,Shiro Motoo

Publisher

Elsevier BV

Subject

Materials Chemistry,Inorganic Chemistry,Physical and Theoretical Chemistry

Reference66 articles.

1. Hydrolysis of phosphate triesters with copper(II) catalysts

2. Metal ion promoted phosphate ester hydrolysis. Intramolecular attack of coordinated hydroxide ion

3. Relationship between effective nucleophilic catalysis in the hydrolysis of esters with poor leaving groups and the lifetime of the tetrahedral intermediate

4. A mononuclear zinc hydroxide complex stabilized by a highly substituted tris(pyrazolyl)hydroborato ligand: analogies with the enzyme carbonic anhydrase

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