Misdirected π-donor ligands: (η5-C5H5)2Zr(Cl) (SR) with sterically more demanding R groups have lower rotational barriers
Author:
Publisher
Elsevier BV
Subject
Materials Chemistry,Inorganic Chemistry,Physical and Theoretical Chemistry
Reference30 articles.
1. Barriers to rotation about the B-X bonds of coordinatively unsaturated borates and thioborates R2BXR' (X = O, S) are not measures of the relative strengths of their B:O and B:S .pi. bonds
2. Control of the reactivity and coordination number of a 16-electron complex by .pi.-donating thiolate ligands
3. Structure and chemistry of bis(cyclopentadienyl)-MLn complexes
4. Single-crystal electron paramagnetic resonance and nonparameterized Fenske-Hall molecular orbital calculations substantiating the demise of the Ballhausen-Dahl bonding model for d1 and d2 M(IV) M(h5-C5H5)2L2
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