Protonation of (2-formylnorbornadiene)cyclopentadienylrhodium.First example of direct transition metal participation in stabilizing of α-carbocationic centre in O-protonated acyl-substituted π-complexes-Reference-Cited by-同舟云学术

Protonation of (2-formylnorbornadiene)cyclopentadienylrhodium.First example of direct transition metal participation in stabilizing of α-carbocationic centre in O-protonated acyl-substituted π-complexes

Published:1985-01 Issue:30 Volume:26 Page:3605-3608
ISSN:0040-4039
Container-title:Tetrahedron Letters
language:en
Short-container-title:Tetrahedron Letters

Author:

Chizhevsky I.T.,Rastova N.V.,Kolobova N.E.,Petrovskii F.V.,Vinogradova L.E.,Leites L.A.

Publisher

Elsevier BV

Subject

Organic Chemistry,Drug Discovery,Biochemistry

Reference14 articles.

1. Protonated ketones as NMR models for organotransition metal cations

2. On the α-carbenium centre stabilization in olefin iron carbonyl complexes. Realization of olefin and allyl structures

3. A commentary on the effect of metal π-complexation on the structures and properties of various pentafulvenes

4. Übergangsmetallfulven-komplexe

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1. Rhodium;Comprehensive Organometallic Chemistry II;1995

2. NMR studies of some η4-diene-rhodium(I) and main group metal derivatives of funtionally substituted cyclopentadienes;Journal of Organometallic Chemistry;1989-04

3. Highly diastereofacial selective chelation of a phosphite-containing .alpha.,.beta.-unsaturated ketone system to the Fe(CO)2 group;Journal of the American Chemical Society;1988-07

4. Cationic hydroxyallylolefin rhodium complexes [Rh(η2, 3-C7H6-3-R-2-CR1OH)(η5-Cp)]+PF6− (R, R1 = H, Alk, Cp = C5H5, C5H4Me, C5Me5) with intramolecular O-H ⋯ Rh hydrogen bonds. Formation of {[CpRh(η2, 3-C7H6-3-R-2-CR1OH)]2-F2POO}+PF6− dimers as a result of partial hydrolysis of the PF6− anion;Journal of Organometallic Chemistry;1988-01

5. Cationic products from O-protonation reaction of 2-acylnorbornadiene complexes of rhodium with hydrogen chloride in ether: structure, reactivity and nature of hydrogen bond;Journal of Organometallic Chemistry;1987-11