On the structures of alpha-lithiated sulfoxide, sulfone and sulfonium systems. Implications for the stereochemistry of functionalization of carbon atoms adjacent to sulfur
Author:
Publisher
Elsevier BV
Subject
Organic Chemistry,Drug Discovery,Biochemistry
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1. A total synthesis of biotin based on the stereoselective alkylation of sulfoxides
2. α-Lithio-δ-sultones: high preference for equatorial vs. axial lithium
3. Stereochemical behavior of .alpha.-lithio sulfoxides (.alpha.-sulfinyl carbanions)
4. The sterochemistry of the reaction of α-lithio-sulphoxides (α-sulphinyl carbanions) with ketones
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