Mono- vs. dialkylation of carbanions. Effects of absolute and relative acidity of the conjugate carbon acids in selectivity control
Author:
Publisher
Elsevier BV
Subject
Organic Chemistry,Drug Discovery,Biochemistry
Reference30 articles.
1. Solvent and leaving group effects on the mono- vs. Dialkylation of alkali salts of diethyl malonate with 1,2-bis-, 1,2,4,5-tetrakis- and 1,2,3,4,5,6-hexakis-(Halomethyl)benzenes. A new insight into selectivity control of malonester synthesis
2. C-C Coupling reaction of 1,5-dibromo-2,6-dihydroxynaphthalene with alkali 2-naphthoxide. Opposite effects of counterion coordination and hydrogen bonding on stereoselectivity in the formation of cis- and trans-1,1′:5′,1″-ternaphthyls
3. Reaction of 1,4-Dibromo-2,3-dihydroxynaphthalene with 2-Naphthoxide Ion. Solvent and Cation Control in the Formation of the Conformationally Locked Stereoisomers of 2,2‘,3‘,2‘‘-Tetrahydroxy-1,1‘:4‘,1‘‘-ternaphthyl and 2,2‘,3‘,2‘‘,3‘‘,2‘‘‘-Hexahydroxy-1,1‘:4‘,1‘‘:4‘‘,1‘‘‘-quaternaphthyl
4. Nucleophilic coupling of alkali 2-naphthoxides with 1-bromo-2 naphthols. Ion-pairing and halogen dance in the formation of 1,1′-binaphthalene-2,2′-diols
5. Stereochemical Dichotomy in the Stevens Rearrangement of Axially Twisted Dihydroazepinium and Dihydrothiepinium Salts. A Novel Enantioselective Synthesis of Pentahelicene
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2. Hydrindacene-Based Acetylenic Macrocycles with Horizontally and Vertically Ordered Functionality Arrays;Chemistry - A European Journal;2013-02-11
3. Organic Crystal Engineering with 1,4-Piperazine-2,5-diones. 8. Synthesis, Crystal Packing, and Thermochemistry of Piperazinediones Derived from 2-Amino-4,7-dialkoxyindan-2-carboxylic Acids;Crystal Growth & Design;2012-09-07
4. Study of the Lithiated Phenylacetonitrile Monoanions and Dianions Formed According to the Lithiated Base Used (LHMDS, LDA, or n-BuLi). 2. Alkylation and Deuteriation Mechanism Study by Vibrational and NMR Spectroscopy and Quantum Chemistry Calculations;The Journal of Organic Chemistry;2012-07-23
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