Separation of the primary and secondary kinetic isotope effects at a reactive center using starting material reactivities. Application to the FeCl3-Catalyzed oxidation of CH bonds with tert-butyl hydroperoxide-Reference-Cited by-同舟云学术

Separation of the primary and secondary kinetic isotope effects at a reactive center using starting material reactivities. Application to the FeCl3-Catalyzed oxidation of CH bonds with tert-butyl hydroperoxide

Published:1999-05 Issue:20 Volume:40 Page:3847-3850
ISSN:0040-4039
Container-title:Tetrahedron Letters
language:en
Short-container-title:Tetrahedron Letters

Author:

Merrigan Steven R.,Le Gloahec Valerie N.,Smith Jason A.,Barton Derek H.R.,Singleton Daniel A.

Publisher

Elsevier BV

Subject

Organic Chemistry,Drug Discovery,Biochemistry

Reference22 articles.

1. How to measure both primary and secondary hydrogen isotope effects in hydrogen abstraction from a substrate having two or more equivalent reactive hydrogen atoms

2. Mechanisms of elimination reactions. 37. Secondary .beta.-tritium isotope effects in eliminations from 2-arylethyl derivatives

3. Isotope effects in hydrogen atom transfer. VII. Benzylic hydrogen abstraction by tert-butoxy and other radicals

4. Kinetic isotope effects for hydrogen abstraction from a series of cycloalkanes and branched alkanes by hydrogen atoms in the gaseous phase

5. Deuterium isotope effect on hydrogen atom abstraction by methyl radicals in acetonitrile at 77 K. Evidence for tunneling

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