A [3.3]Sigmatropic Rearrangement of α,β-Unsaturated Fischer Chromium Carbenes: Synthesis of Alkynol and Dienol Esters
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Publisher
Elsevier BV
Subject
Organic Chemistry,Drug Discovery,Biochemistry
Reference51 articles.
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2. To our knowledge, pentacarbonyl[1-acyloxy-(2-furyl)methylidene]chromium(0) and pentacarbonyl[1-acyloxy-(2-thienyl)methylidene]chromium(0) are the only acyloxy chromium complexes isolable at room temperature. (a) Connor, J. A.; Jones, E. M. J. Chem. Soc. A1971, 1974–1979. (b) Fischer, E. O.; Selmayr, T.; Kreißl, F. R. Chem. Ber.1977, 110, 2947–2955. For an attempted intramolecular benzannulation of a related furyl complex, see: Wulff, W. D.; McCallum, J. S.; Kunng, F.-A. J. Am. Chem. Soc.1988, 110, 7419–7434.
3. Thermally stable acyloxy complexes of iron and ruthenium have been reported: Adams, H.; Maloney, C. A.; Muir, J. E.; Walters, S. J.; Winter, M. J. J. Chem. Soc., Chem. Commun., 1995, 1511–1512.
4. (a) Takeda, K.; Okamoto, Y.; Nakajima, A.; Yoshii, E.; Koizumi, T. Synlett1997, 1181–1183.
5. (b) Murray, C. K.; Yang, D. C.; Wulff, W. D. J. Am. Chem. Soc.1990, 112, 5660–5662.
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