Ring opening in the reaction of diphenylcyclopropane derivatives with strong base: evidence for a proton transfer and against an electron transfer reaction. Facile disrotatory ring opening of a cyclopropyl anion at -75°C
Author:
Publisher
Elsevier BV
Subject
Organic Chemistry,Drug Discovery,Biochemistry
Reference24 articles.
1. Ring opening reactions of triphenylcyclopropyl anions. II. Apparent disrotatory opening of a cyclopropyl anion
2. Reaction of organolithium compounds with a triphenylcyclopropyl derivative. The matter of cyclopropyl anion ring opening
3. Evidence for a radical-anion pathway of a phenylcyclopropyl ring cleavage in the presence of potassium tert-butoxide
4. Evidence for single electron transfer in the reations of alkali metal amides and alkoxides with alkyl halides and polynuclear hydrocarbons
5. Ringöffnung von 2,3‐Diphenylcyclopropyl‐ zu 1,3‐Diphenyl‐allyllithium‐Verbindungen
Cited by 5 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献
1. Unimolecular rearrangements of carbanions in the gas phase. 2. Cyclopropyl anions;Journal of the American Chemical Society;1993-01
2. Preparation and ring-opening of benzylic and allylic cyclopropyl dianions;The Journal of Organic Chemistry;1992-06
3. Reinvestigation of the metalation of phenylcyclopropane: does the phenylcyclopropyl anion undergo ring-opening?;The Journal of Organic Chemistry;1988-09
4. ChemInform Abstract: RING OPENING IN THE REACTION OF DIPHENYLCYCLOPROPANE DERIVATIVES WITH STRONG BASE: EVIDENCE FOR A PROTON TRANSFER AND AGAINST AN ELECTRON-TRANSFER-INITIATED REACTION. FACILE DISROTATORY RING OPENING OF A CYCLOPROPYL ANION AT -75°;Chemischer Informationsdienst;1983-12-06
5. Rearrangements of “Carbanions”;Topics in Current Chemistry
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