Catalytic reductive ring opening of epoxides enabled by zirconocene and photoredox catalysis

Author:

Aida Kazuhiro,Hirao Marina,Funabashi Aiko,Sugimura Natsuhiko,Ota Eisuke,Yamaguchi Junichiro

Publisher

Elsevier BV

Subject

Materials Chemistry,Biochemistry (medical),General Chemical Engineering,Environmental Chemistry,Biochemistry,General Chemistry

Reference80 articles.

1. Reductive ring opening of epoxides with dissolving metals (see, Birch,2 Hallsworth and Henbest,3 Brown et al.,4 and Benkeser et al.5) or with stoichiometric arene radical anions (Bartmann,6 Drigo et al.,7 and Cohen et al.8) also afford carbon radicals which is further reduced to exhibit carbanion reactivity.

2. Reduction by dissolving metals. Part VIII. Some effects of structure on the course of reductive fission;Birch;J. Proc. R. Soc. NSW,1949

3. 924. Aspects of stereochemistry. Part VII. Metal reduction of vicinal epoxycyclohexanes;Hallsworth;J. Chem. Soc.,1957

4. Additions to bicyclic olefins. IV. Facile reduction of labile epoxides of bicyclic olefins by lithium in ethylenediamine;Brown;J. Org. Chem.,1970

5. Calcium and lithium reductions of epoxides in ethylenediamine. A comparison study;Benkeser;J. Org. Chem.,1986

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