Synthesis and reactions of phosphido-bridged μ3-alkylidyne clusters; X-ray crystal structures of the complexes [Co2W(μ-PEt2)3(CO)5(η-C5H5)], [Co2W{μ3-C(R)C(Et)C(Et)C(O)}(μ-CO)(CO)4(PPh2{C(Et)CHEt})(η-C5H5)], and [CoW{μ-C(R)C(Et)C(Et)C(OH)}(CO)4(η-C5H5)] (R = C6H4Me-4)-Reference-Cited by-同舟云学术

Synthesis and reactions of phosphido-bridged μ3-alkylidyne clusters; X-ray crystal structures of the complexes [Co2W(μ-PEt2)3(CO)5(η-C5H5)], [Co2W{μ3-C(R)C(Et)C(Et)C(O)}(μ-CO)(CO)4(PPh2{C(Et)CHEt})(η-C5H5)], and [CoW{μ-C(R)C(Et)C(Et)C(OH)}(CO)4(η-C5H5)] (R = C6H4Me-4)

Published:1986-09 Issue:3 Volume:311 Page:C55-C59
ISSN:0022-328X
Container-title:Journal of Organometallic Chemistry
language:en
Short-container-title:Journal of Organometallic Chemistry

Author:

Dunn Paul,Jeffery John C.,Sherwood Paul

Publisher

Elsevier BV

Subject

Materials Chemistry,Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference6 articles.

1. Reactivity patterns of heterobinuclear carbonyls: site selectivity in substitution reactions of (CO)4Ru(.mu.-PPh2)Co(CO)3 with phosphines and the x-ray structure of (Ph3P)Ru(CO)3(.mu.-PPh2)Co(CO)3

2. Synthesis of μ-hydrido-μ-phosphido heterotrimetal alkylidyne clusters: X-ray crystal structure of [Co2W(μ-H)(μ3-CMe)(μ-PPh2)(CO)6(η-C5H5]

3. Synthesis and molecular structure of [Rh3 (μ-PPh2)3(CO)5], an edge-bridged triangular cluster of rhodium

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1. Phosphorus–hydrogen bond cleavage on a Ph2PH-substituted μ3-thioxo dicobalt–iron cluster as a route to bridging phosphido and thiophosphine ligands;Journal of Organometallic Chemistry;2002-01

2. Alkyne–phosphinoalkyne coupling reactions on mixed-metal tungsten–cobalt centres; P–C(alkyne) bond cleavage versus P–C(alkyne) bond preservation;Journal of the Chemical Society, Dalton Transactions;2001

3. Synthesis and Structure of the Cluster Ion Pair {Ru3(CO)9[μ-P(NPri2)2]3}{Ru6(CO)15(μ6-C)[μ-P(NPri2)2]}. A Theoretical Overview of M3(μ-PR2)3 Frameworks;Inorganic Chemistry;2000-02-18

4. “Very mixed”-metal carbonyl clusters;Advances in Organometallic Chemistry;2000

5. Reactivity of Alkynyl Platinum Complexes towards PPh2H and PPh2(O)H: Unexpected Formation of Alkynyl Tetralithium Diplatinum Compounds Stabilized byμ3-(κ3P,O,O-PPh2O−) Ligands;Chemistry - A European Journal;1999-02-01