The reaction in acetonitrile between PdCl2 and the carbonyl-stablized ylide Ph3PCHCO2Me. Synthesis of [P6H4)Ph2}(CO2Me)}(μ-Cl)]2 and some of its derivatives and of [PdCl2{CH(PPh3)CO2Me}2]
Author:
Publisher
Elsevier BV
Subject
Materials Chemistry,Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Reference9 articles.
1. Keto-stabilized phosphorus ylide gold(I) and gold(III) complexes
2. Synthesis of silver(I) complexes with carbonyl-stabilized phosphorus ylides: crystal structures of two [Ag{;CH(PPh3)C(O)R};2]+ derivatives
3. Synthesis of gold(I), gold(III), and silver(I) complexes with ylide ligands derived from carbonylbis(methylenetriphenylphosphonium)diperclorate. Crystal and molecular structures of [Au2{.mu.-{{CH(PPh3)}2CO}}2](ClO4)2, [(Ph3PCCl2)2CO][AuCl4](ClO4), [(AuL)2{.mu.-{C(PPh3)C(O)CH(PPh3)(AuL)}}](ClO4)2 (L = PPh3), and [{Au(PMe2Ph)}4{.mu.-{{C(PPh3)}2CO}}](ClO4)2
4. Palladium(II), platinum(II) and mercury(II) complexes of ambidentate phosphonium, arsonium, sulfonium and pyridinium ylids
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