Reaction of iron dicarbonyl phosphine complexes of 2-(phenylazo)pyridines with dimethyl acetylenedicarboxylate. Synthesis and crystal structure of a 2,3,1-diazaferrole complex-Reference-Cited by-同舟云学术

Reaction of iron dicarbonyl phosphine complexes of 2-(phenylazo)pyridines with dimethyl acetylenedicarboxylate. Synthesis and crystal structure of a 2,3,1-diazaferrole complex

Published:1996-09 Issue:1 Volume:522 Page:105-115
ISSN:0022-328X
Container-title:Journal of Organometallic Chemistry
language:en
Short-container-title:Journal of Organometallic Chemistry

Author:

Ackermann Martin N.,Mikulec Frederic V.,Matzger Adam J.,Antonio Barbara J.,Barron M.Christopher,Todd Melissa J.,Meeker Kathleen,Chupa Angeline L.,Woods Clifton

Publisher

Elsevier BV

Subject

Materials Chemistry,Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference21 articles.

1. 1,5-Dihydropyrrol-2-ones from (1,4-diaza-1,3-diene)tricarbonyliron, (DAD)Fe(CO)3, and alkyne. 5. Spectroscopic and x-ray structural characterization of a bicyclo[2.2.1] complex resembling the initial cycloadduct. The C = N-Fe fragment in (DAD)Fe(CO)3 as an isolobal analog of the classical 1,3-dipole azomethine ylide in 1,3-dipolar cycloaddition

2. 1,3-Dipolar cycloaddition reactions to the C:XM fragment. 7. The reaction of Ru(CO)3(iso-Pr-DAB) with dimethyl acetylenedicarboxylate. X-ray crystal structure of the protonated initial bicyclo[2.2.1] adduct

3. 1,3-Dipolar cycloaddition to the C=N-Fe fragment. 6. Formation of 1,4,3a,6a-tetrahydropyrrolo[3,2-b]pyrrole through double addition of dimethyl acetylenedicarboxylate to (1,4-diisopropyl-1,4-diaza-1,3-butadiene)(tert-butylisocyanide)dicarbonyliron, utilizing both imine units of the 1,4-diaza-1,3-butadiene ligand

4. 1,3-Dipolar cycloaddition to the iron-imine (Fe-N:C) fragment. 8. Formation of 1,4,3a,6a-tetrahydropyrrolo[3,2-b]pyrroles via double 1,3-dipolar cycloaddition of alkynes to Fe(CO)2(CNR)(.alpha.-diimine). Competition between isocyanide and CO insertion. Determination of cone angles of isocyanides

5. 1,3-Dipolar cycloaddition to the iron-imine (Fe-N:C) fragment. 10. Synthesis of Fe(CNR)3(.alpha.-diimine) complexes and their reactivity toward dimethyl acetylenedicarboxylate