Base-free cationic 14-electron alkyls of Ti, Zr and Hf as polymerisation catalysts: A comparison
Author:
Publisher
Elsevier BV
Subject
Materials Chemistry,Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Reference35 articles.
1. Organometallic compounds of Group III. Part 41. Direct observation of the initial insertion of an unsaturated hydrocarbon into the titanium-carbon bond of the soluble Ziegler polymerization catalyst Cp2TiCl2-MeAlCl2
2. Cationic alkylbis(cyclopentadienyl)titanium complexes. Synthesis, reactions with carbon monoxide and tert-butyl isocyanide, and the structure of [Cp2Ti[.eta.2-C(Me)NBu-tert](CNBu-tert)]BPh4.MeCN
3. Insertion reactions of nitriles in cationic alkylbis(cyclopentadienyl)titanium complexes: the facile synthesis of azaalkenylidene titanium complexes and the crystal and molecular structure of [(indenyl)2Ti(NCMePh)(NCPh)]BPh4
4. Synthesis of cationic alkyl bis(cyclopentadienyl)titanium complexes by one-electron oxidation of titanium(III) alkyls. The structure of [Cp2*TiMe(THF)]BPh4 and [Cp2*Ti(OH)(H2O)]BPh4·2THF
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