Formation of group 11 trifluoromethyl derivatives by reaction of Cd(CF3)2·glyme with representative Au, Ag, and Cu complexes: isolation of Au(CF3)3(PMe3), Au(CF3)3(PEt3), AuI(CF3)2(PMe3), AuCF3(PMe3), AuCF3(PEt3) and AgCF3(PMe3); observation of CuCF3(PMe3)-Reference-Cited by-同舟云学术

Formation of group 11 trifluoromethyl derivatives by reaction of Cd(CF3)2·glyme with representative Au, Ag, and Cu complexes: isolation of Au(CF3)3(PMe3), Au(CF3)3(PEt3), AuI(CF3)2(PMe3), AuCF3(PMe3), AuCF3(PEt3) and AgCF3(PMe3); observation of CuCF3(PMe3)

Published:1989-10 Issue:1 Volume:376 Page:149-164
ISSN:0022-328X
Container-title:Journal of Organometallic Chemistry
language:en
Short-container-title:Journal of Organometallic Chemistry

Author:

Nair H.K.,Morrison J.A.

Publisher

Elsevier BV

Subject

Materials Chemistry,Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference32 articles.

1. Bis(trifluoromethyl)cadmium·glyme (glyme = dimethoxyethane), a new, powerful fluoroalkylating agent and low-temperature source of difluorocarbene

2. Trifluoromethyl group 2B compounds: bis(trifluoromethyl)cadmium.base. New, more powerful ligand-exchange reagents and low-temperature difluorocarbene sources

3. Trifluoromethyl Group 2Bcompounds: formation of mono- and bis-(trifluoromethyl)–platinum, –palladium, and –nickel trialkylphosphine complexes from the reaction of (CF3)2Cd·glyme [glyme =(CH2OMe)2] with the diligand metal dihalides

4. Preparation and properties of (.eta.5-C5H5)Co(CO)(CF3)2. The reaction of (CF3)2Cd.cntdot.glyme with CpCo(CO)I2

5. Preparation of bis(trifluoromethyl)tellurium, bis(trifluoromethyl)selenium, bis(trifluoromethyl)diselenium, tris(trifluoromethyl)antimony, tris(trifluoromethyl)arsine, bis(trifluoromethyl)arsenic iodide, tris(trifluoromethyl)phosphine, and (trifluoromethyl)phosphorus diiodide by reaction of bis(trifluoromethyl)mercury with the Group 5 and 6A (15 and 16) halides

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