Double oxidative addition of CH bonds on a triruthenium cluster complex; synthesis and characterization of Ru3{μ-H2,η2,μ3-C(OEt)=C(H)}(CO)9 and Ru3{μ-H2,η2,μ3-C(OEt)N(Me)C(CH)}(CO)9-Reference-Cited by-同舟云学术

Double oxidative addition of CH bonds on a triruthenium cluster complex; synthesis and characterization of Ru3{μ-H2,η2,μ3-C(OEt)=C(H)}(CO)9 and Ru3{μ-H2,η2,μ3-C(OEt)N(Me)C(CH)}(CO)9

Published:1987-08 Issue:1-2 Volume:330 Page:133-154
ISSN:0022-328X
Container-title:Journal of Organometallic Chemistry
language:en
Short-container-title:Journal of Organometallic Chemistry

Author:

Jensen Craig M.,Kaesz Herbert D.

Publisher

Elsevier BV

Subject

Materials Chemistry,Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference39 articles.

1. Double oxidative addition of beta or gamma methyl groups of coordinated Fischer-type carbenes on a tri-ruthenium cluster; synthesis of Ru3{.mu.-H2,.eta.2,.mu.3-C(OEt):C(H)}(CO)9 and Ru3{.mu.-H2,.eta.2,.mu.3-C(OEt)N(Me)C(H)}(CO)9

2. Alkylation of salts of the triosmium anions [Os3(eq-.eta.1-COMe)(CO)11]-, [Os3(.mu.-O:CMe)(CO)10]- and [Os3(COR)(.mu.-H;.mu.-O:CMe)(CO)9]- (R = Me or Ph). Crystal and molecular structure of Os3(1-.eta.1-CMeOMe)(1,2-.mu.-H;1,2-.mu.-O:CMe)(CO)9

3. Synthesis of edge double-bridged Ru3(.mu.-H,.mu.-X)(CO)10, X = O:C(Me), Cl, Br, I, and of Ru3(.mu.-H,.mu.3-I)(CO)9: a new series of reactive complexes for triruthenium cluster chemistry. Crystal and molecular structure of Ru3(.mu.-H,.mu.-Br)(CO)10

4. Hydride complexes of the transition metals

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1. Reactions of Ru5(μ5-C2PPh2)(μ-PPh2)(CO)13 with functional phosphines. X-ray structures of Ru5(μ5-C2PPh2)(μ-PPh2)(dppm)(CO)12·CHCl3Ru5(μ5-C2H)(μ-PPh2)2(μ-P,N-PPh2H4NH-2)(μ-CO)(CO)10, Ru4{μ4-C4PPh2[Ru(μ-OH)(C,P-2-CHMeC6PPh2-2) (CO)2]}(μ-PPh2)(CO)10·CHCl3 and Ru4(μ-H)2{μ5-PPh2C2CHC)C6H4PPh2-2)}(μ-PPh2)(CO)11;Journal of Organometallic Chemistry;1996-05

2. 47-Electron Organometallic Clusters. Synthesis, Characterization, and Reactivity toward Electrophiles/Oxidants of H2Ru3(RC2R')(CO)6(PPh3)3 and Crystal Structures of (.mu.-H)2Ru3(.mu.3-.eta.2-EtCCEt)(CO)7(PPh3)2 and (.mu.-H)2Ru3(.mu.3-.eta.2-EtCCEt)(CO)6(PPh3)3.cntdot.3CH2Cl2;Organometallics;1995-08

3. Trinuclear Clusters of Ruthenium and Osmium: (iii) Clusters with Metal–Carbon Bonds to Heteroatom Ligands;Comprehensive Organometallic Chemistry II;1995

4. Trinuclear Clusters of Ruthenium and Osmium: (ii) Hydrocarbon Ligands on Metal Clusters;Comprehensive Organometallic Chemistry II;1995

5. Trinuclear Clusters of Ruthenium and Osmium: (i) Introduction and Simple Neutral, Anionic and Hydrido Clusters;Comprehensive Organometallic Chemistry II;1995