Syntheses and 31P NMR studies of ruthenium(II), rhodium(I), and rhodium(III) complexes containing η5-P2C3tBu3 and η5- and η1-P3C2tBu2 ligated ring systems. Crystal structures of [Rh(η5-P2C3tBu3)(η4-COD)] (COD = 1,5-cyclooctadiene) and the novel hydrido-η1-triphosphacyclopentadienyl complex [RhH(η1-P3C2tBu2)(η5C5Me5)PPh3]-Reference-Cited by-同舟云学术

Syntheses and 31P NMR studies of ruthenium(II), rhodium(I), and rhodium(III) complexes containing η5-P2C3tBu3 and η5- and η1-P3C2tBu2 ligated ring systems. Crystal structures of [Rh(η5-P2C3tBu3)(η4-COD)] (COD = 1,5-cyclooctadiene) and the novel hydrido-η1-triphosphacyclopentadienyl complex [RhH(η1-P3C2tBu2)(η5C5Me5)PPh3]

Published:1993-12 Issue:1-2 Volume:462 Page:319-329
ISSN:0022-328X
Container-title:Journal of Organometallic Chemistry
language:en
Short-container-title:Journal of Organometallic Chemistry

Author:

Hitchcock Peter B.,Matos Robson M.,Nixon John F.

Publisher

Elsevier BV

Subject

Materials Chemistry,Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference43 articles.

1. Cleavage of the pc triple bond in a phospha-alkyne in the absence of a transition metal

2. First structural characterisation of penta- and hexa-phosphorus analogues of ferrocene. Synthesis, crystal and molecular structure of the air-stable, sublimable iron sandwich compounds [Fe(η5-C2R2P3)2], and [Fe(η5-C3R3P2)(η5-C2R2P3)](R = But)

3. Hexa-phosphorus analogues of metallocenes: synthesis of the first paramagnetic sandwich complex containing two η51,2,4-triphosphacyclopentadienyl rings. Crystal and molecular structures of [Cr(η5-C2But2P3)2]

4. Synthesis, crystal and molecular structure of the “slipped” sandwich complex [Ni(η5-P3C2R2)(η3-P2C3R3)] (R = But)

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