Mixed-ligand systems containing quadruple bonds. Capture and structural characterization of an intermediate in the ligand exchange process leading to new carboxylates of the dimolybdenum(4+ unit. Synthesis and X-ray crystallographic and electrochemical studies of Mo2[(η5-C5H4CO2)Fe(η5-C5H5)]2(O2CCH3)2(C5H5N)2 and [Mo2](η5-C5H4CO2)Fe(η5-C5H5)]4(ax-CH3CN)(ax-DMSO)](DMSO)2-Reference-Cited by-同舟云学术

Mixed-ligand systems containing quadruple bonds. Capture and structural characterization of an intermediate in the ligand exchange process leading to new carboxylates of the dimolybdenum(4+ unit. Synthesis and X-ray crystallographic and electrochemical studies of Mo2[(η5-C5H4CO2)Fe(η5-C5H5)]2(O2CCH3)2(C5H5N)2 and [Mo2](η5-C5H4CO2)Fe(η5-C5H5)]4(ax-CH3CN)(ax-DMSO)](DMSO)2

Published:1987-01 Issue:1 Volume:319 Page:87-97
ISSN:0022-328X
Container-title:Journal of Organometallic Chemistry
language:en
Short-container-title:Journal of Organometallic Chemistry

Author:

Cotton F.A.,Falvello L.R.,Reid A.H.,Tocher J.H.

Publisher

Elsevier BV

Subject

Materials Chemistry,Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference37 articles.

1. Sensitivity of the chromium-chromium quadruple bond in dichromium tetracarboxylates to axial coordination and changes in inductive effects

2. Metal-metal bonded complexes of the early transition metals. 2. Synthesis of quadruply bonded tungsten(II) trifluoroacetate complexes

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