Coordination of the potentially tridentate ligands 2,6-diacetylpyridine-bis(anil) (dapa) and 2-(2-(2′-methylidenepyridyl) aminoethyl) pyridine (map) in the complexes fac-BrMn(CO)3 L, fac-(CO)5MM′(CO)3L (M, M′= Mn, Re; L = dapa, map) and their photoproducts. The crystal structure of BrMn(CO)2(N,N,N-dapa)-Reference-Cited by-同舟云学术

Coordination of the potentially tridentate ligands 2,6-diacetylpyridine-bis(anil) (dapa) and 2-(2-(2′-methylidenepyridyl) aminoethyl) pyridine (map) in the complexes fac-BrMn(CO)3 L, fac-(CO)5MM′(CO)3L (M, M′= Mn, Re; L = dapa, map) and their photoproducts. The crystal structure of BrMn(CO)2(N,N,N-dapa)

Published:1994-11 Issue:1-2 Volume:482 Page:15-29
ISSN:0022-328X
Container-title:Journal of Organometallic Chemistry
language:en
Short-container-title:Journal of Organometallic Chemistry

Author:

Stor G.J.,van der Vis M.,Stufkens D.J.,Oskam A.,Fraanje J.,Goubitz K.

Publisher

Elsevier BV

Subject

Materials Chemistry,Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference43 articles.

1. Photochemistry of metal-metal bonded complexes. 5. Cleavage of the M-M bond in (OC)5M-M(CO)3L by irradiation into a low-lying M .fwdarw. L charge-transfer band

2. Photochemistry of metal-metal-bonded complexes. 1. MLCT photolysis of (CO)5MM'(CO)3(.alpha.-diimine) (M, M' = Mn, Re) in 2-MeTHF between 133 and 230 K

3. Photochemistry of metal-metal-bonded complexes. 2. MLCT(metal-ligand charge transfer) photochemistry of (CO)5MM'(CO)3(R-DAB) (M, M' = Mn, Re; DAB = 1,4-diaza-1,3-butadiene) in inert-gas matrixes at 10 K and in PVC film at 193 and 293 K

4. Photochemistry of metal—metal bonded complexes

5. Metal to ligand charge-transfer photochemistry of metal-metal-bonded complexes. 8. Photochemistry of (pentacarbonylmanganese)tricarbonyl(.alpha.-diimine)manganese complexes. Coupling reactions of the radicals formed and x-ray structure of the photoproduct (CO)4Mn(.sigma.-N,.sigma.-N',.eta.2-CN-iso-Pr-PyCa)Mn(CO)3 (iso-Pr-PyCa = pyridine-2-carbaldehyde-N-isopropylimine).

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