Reactions of di- and poly-nuclear complexes. 12 . Synthesis and thermal decomposition reactions of tetranuclear clusters [Co4Cp2(CO) 5-nLn(RC2R′)] (L = PPh2H; n = 0, 1 or 2) (R = R′ = CF3, C6F5, C6H5 or Me; R = H, R′ = CF3).
Author:
Publisher
Elsevier BV
Subject
Materials Chemistry,Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Reference29 articles.
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2. Reactions of di- and polynuclear complexes. 7. Reaction of [cyclic] [(CO)3Co(.mu.-RC2R')Co(CO)3] (R = R' = CF3, CO2Me; R = CF3, C6H5 and R' = H) with [{FeCp(CO)2}2]. Di- and tetranuclear mixed-metal complexes. Alkyne coordination and scission by a tetrametallic framework. Crystal structures of [Co3FeCp(.mu.4-.eta.2-C:CHCF3)(.eta.6-C7H8)(.mu.-CO)2(CO)4] and [Co3FeCp2(.mu.4-.eta.2-C.tplbond.CCF3)(.mu.-CO)(CO)5]
3. Carbon–carbon triple bond cleavage at room temperature with nonacarbonyldi-iron: synthesis of [Fe3(CO)9(µ3-CMe)(µ3-CNEt2)]
4. Azoalkane-Nitrene Cleavage on an Fe3-Cluster
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4. Reactions of dinuclear and polynuclear complexes XIX. Rearrangements of terminal or disubstituted alkyne ligands present in homo- and heterodinuclear complexes of cobalt and molybdenum during reactions with molybdenum and cobalt carbonyl compounds: formation of trinuclear and tetranuclear clusters;Journal of Organometallic Chemistry;1998-03
5. Homogeneous and solid-gas hydrogenation of alkynes in the presence of the clusters Fe-3(CO)(9)(mu-RC2R1) {R = R-1 = Ph, Et; R = Me, R-1 = Ph}: Characterization of new metallacyclic derivatives;Journal of Cluster Science;1998
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