Use of coordinated phosphaalkyne ligands in transition metal cluster interlinkage. Synthesis of dimolybdenum-triruthenium and dimolybdenum-triosmium complexes [Mo2M3(η5-C5H5)2(CO)15(tBuCP)], (M = Ru, Os) and crystal and molecular structure of di-η5-cyclopentadienyltetracarbonyl-μ-(3,3-dimethyl-1-phosphabutyne)-triangulo-triosmium(O), [Mo2(η5-C5H5)2(CO)4(μ-tBuCP)Os3(CO)11]-Reference-Cited by-同舟云学术

Use of coordinated phosphaalkyne ligands in transition metal cluster interlinkage. Synthesis of dimolybdenum-triruthenium and dimolybdenum-triosmium complexes [Mo2M3(η5-C5H5)2(CO)15(tBuCP)], (M = Ru, Os) and crystal and molecular structure of di-η5-cyclopentadienyltetracarbonyl-μ-(3,3-dimethyl-1-phosphabutyne)-triangulo-triosmium(O), [Mo2(η5-C5H5)2(CO)4(μ-tBuCP)Os3(CO)11]

Published:1984-05 Issue:3 Volume:266 Page:c41-c43
ISSN:0022-328X
Container-title:Journal of Organometallic Chemistry
language:en
Short-container-title:Journal of Organometallic Chemistry

Author:

Bartsch Rainer,Hitchcock Peter B.,Meidine Mohamed F.,Nixon John F.

Publisher

Elsevier BV

Subject

Materials Chemistry,Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference8 articles.

1. Novel transition metal phospha-alkyne complexes: tBuCP acting as a 6 electron donor ligand. Synthesis, crystal and molecular structure of [Co2(CO)6(μ-tBuCP)W(CO)5]

2. P.B. Hitchcock, S.I. Klein, M.F. Meidine and J.F. Nixon. unpublished results.

3. Transformations of the heteronuclear clusters En[Co(Co)3]4−n (E = P, As; n = 1–3) when treated with soft lewis acids and bases

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1. Hydrometalation of P⋮CBut and Activation of the P−C Bond by a Tetrairidium Carbonyl Cluster: Solution Characterization of [Ir4Pt(dppe)(CO)n{μ-PC(H)But}(μ-PPh2)] (n = 10 and 9) and Crystal and Molecular Structures of the Phosphinidine Complex [HIr4Pt(dppe)(μ-CO)(CO)7(μ-PCH2But)(μ-PPh2)] and of the Partially Encapsulated Phosphide Compound [Ir4Pt(dppe)(μ-CO)(CO)8(μ5-P)(μ-PPh2)];Organometallics;1998-11-07

2. Recent developments in the organometallic chemistry of phospha-alkynes, RCP;Coordination Chemistry Reviews;1995-11

3. Synthesis and Characterization of a Phosphaalkyne-Bridged Pentairon Carbonyl Cluster. Crystal and Molecular Structure of [{Fe3Se2(CO)8}(.mu.-PCBut){Fe2Se(CO)6}];Organometallics;1995-06

4. Phospha-alkynes, RCP: new building blocks in inorganic and organometallic chemistry;Chem. Soc. Rev.;1995

5. Synthesis and 31P and 195Pt NMR characterisation of the first binuclear platinum(I) complex [Pt2Cl2(μ-dppm)2(μ-ButCP)] containing a μ-parallel ligated phospha-alkyne;Inorganica Chimica Acta;1993-10