Alkyl- und arylkomplexe des iridiums und rhodiums XII. Phosphitinduzierte co-insertions- und C H-additionsreaktionen ortho-alkylsubstituierter iridiumaryle: synthese und struktur zweier metallazyklischer verbindungen HR-2][P(OMe)3]3 (R CH3, H)
Author:
Publisher
Elsevier BV
Subject
Materials Chemistry,Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Reference15 articles.
1. Ligandeninduzierte intramolekulare oxidative Additionen von Methyl‐C H‐Bindungen: ortho ‐methylsubstituierte Arylkomplexe des Iridiums(I) und deren Reaktionen mit Phosphinen und Phosphiten
2. Cyclometallation reactions inortho-methyl substituted iridium arylsvia CO insertion and oxidative C-H addition. Characterization of the reported IrH[C6H2Me2-(4,6)-CH2-(2)][P(OMe)3]3 as the internally metallated benzoyl complexfac-IrH[C(O)C6H2Me2-(4,6)-H2(2)]-[P(OMe)3]3 by X-Ray diffraction(1)
3. Cyclometallierungsreaktionen
4. Cyclometalation Reactions
5. Hydridometallacycloalkane complexes of iridium. Unassisted intramolecular distal carbon-hydrogen bond activation
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