Molecular structure of the MoMo triple-bonded pentamethylcyclopentadienylmolybdenum dimer, Mo2(η5-C5Me5)2(CO)4, and its geometrical relationship with the nonmethylated cyclopentadienyl analogue (MoMo) and corresponding chromium dimers (CrCr)-Reference-Cited by-同舟云学术

Molecular structure of the MoMo triple-bonded pentamethylcyclopentadienylmolybdenum dimer, Mo2(η5-C5Me5)2(CO)4, and its geometrical relationship with the nonmethylated cyclopentadienyl analogue (MoMo) and corresponding chromium dimers (CrCr)

Published:1983-02 Issue:1 Volume:243 Page:57-68
ISSN:0022-328X
Container-title:Journal of Organometallic Chemistry
language:en
Short-container-title:Journal of Organometallic Chemistry

Author:

Huang Jin-Shun,Dahl Lawrence F.

Publisher

Elsevier BV

Subject

Materials Chemistry,Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference61 articles.

1. Synthesis, crystal structure, and stereochemical characterization of [Co4(η5-C5Me5)2(CO)4(µ2-CO)(µ3-CO)2]: a completely bonding tetrahedral cobalt cluster formed from a cobalt–cobalt multiple-bonded dimer

2. Photochemical formation and stereochemical characterization of two electronically equivalent but structurally different series of triangular dicobalt-metal clusters, MCo2(.eta.5-C5Me5)2(.mu.-CO)3(.mu.3-CO) [M = Cr(.eta.6-C6H5Me), Mn(.eta.5-C5H4Me), Fe(.eta.4-C4H4)] and MCo2(.eta.5-C5Me5)2(.mu.-CO)2(.mu.3-CO) [M = Fe(CO)3, Co(.eta.5(C5H4Me)]: a rational synthesis of mixed-metal clusters by photogenerated metal-fragment addition across a metal-metal multiple-bonded dimer

3. Pentamethylcyclopentadienyl cobalt carbonyl dimers containing multiple metal–metal bond character: preparation, structural analysis (including X-ray crystallographic determinations), and bonding implications of [Co2(η5-C5Me5)2(µ2-CO)2]n(n=–1 or 0)

4. Crystal and molecular structure of bis(pentamethylcyclopentadienyl)dicarbonyldicobalt

5. Synthesis, stereochemistry, and bonding of cobalt-cobalt multiple-bonded (pentamethylcyclopentadienyl)- and cyclopentadienylcobalt carbonyl dimers, [Co2(.eta.5-C5R5)2(.mu.-CO)2]n (R = Me, n = 0,1-; R = H, n = 1-): a comparative analysis of the antibonding dimetal nature of the unpaired electron in the monoanions and its structural effects upon oxidation

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1. Binuclear heterometallic bonding between a first row transition metal and a second row transition metal: The cyclopentadienyliron molybdenum carbonyls Cp2FeMo(CO) (n = 6, 5, 4, 3, 2);Inorganica Chimica Acta;2019-07

2. Agostic hydrogen atoms versus cobalt-cobalt multiple bonding in binuclear borole cobalt carbonyls;Inorganica Chimica Acta;2019-03

3. Metal-metal interactions in binuclear cyclopentadienylmetal carbonyls: Extending insight from experimental work through computational studies;Computational Chemistry;2019

4. Metal-metal bonding in biscycloheptatrienyl dimetal compounds of the second-row transition metals;International Journal of Quantum Chemistry;2017-03-23

5. Bridging hydrogen atoms versus iron–iron multiple bonding in binuclear borole iron carbonyls;Inorganica Chimica Acta;2016-06