Biosynthesis of monoterpenes. Enantioselectivity in the enzymatic cyclization of (+)- and (-)-linalyl pyrophosphate to (+)- and (-)-pinene and (+)- and (-)-camphene.-Reference-Cited by-同舟云学术

Biosynthesis of monoterpenes. Enantioselectivity in the enzymatic cyclization of (+)- and (-)-linalyl pyrophosphate to (+)- and (-)-pinene and (+)- and (-)-camphene.

Published:1988-07 Issue:21 Volume:263 Page:10063-10071
ISSN:0021-9258
Container-title:Journal of Biological Chemistry
language:en
Short-container-title:Journal of Biological Chemistry

Author:

Croteau R,Satterwhite D M,Cane D E,Chang C C

Publisher

Elsevier BV

Subject

Cell Biology,Molecular Biology,Biochemistry

Reference40 articles.

1. Biosynthesis of (+/-)-alpha-pinene and (-)-beta-pinene from geranyl pyrophosphate by a soluble enzyme system from sage (Salvia officinalis).

2. Pinene cyclases I and II. Two enzymes from sage (Salvia officinalis) which catalyze stereospecific cyclizations of geranyl pyrophosphate to monoterpene olefins of opposite configuration.

3. Isotopically sensitive branching in the formation of cyclic monoterpenes: proof that (-)-.alpha.-pinene and (-)-.beta.-pinene are synthesized by the same monoterpene cyclase via deprotonation of a common intermediate

4. [44] Monoterpene and sesquiterpene cyclases

5. Isoprenoid biosynthesis. Stereochemistry of the cyclization of allylic pyrophosphates

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