How do dimethyl oxalate ions CH3O-C(=O)-C(=O)-OCH3·+ break in half? Loss of CH3· + CO2 versus CH3O-C-O·-Reference-Cited by-同舟云学术

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How do dimethyl oxalate ions CH3O-C(=O)-C(=O)-OCH3·+ break in half? Loss of CH3· + CO2 versus CH3O-C-O·

Published:1999-09-01 Issue:9 Volume:10 Page:869-877
ISSN:1044-0305
Container-title:Journal of the American Society for Mass Spectrometry
language:en
Short-container-title:J. Am. Soc. Mass Spectrom.

Author:

Trikoupis Moschoula A.¹,Terlouw Johan K.¹,Burgers Peter C.²,Peres Menechem³,Lifshitz Chava³

Affiliation:

1. Department of Chemistry, McMaster University, Hamilton, Ontario, Canada

2. Hercules European Research Center, Barneveld, The Netherlands

3. Department of Physical Chemistry and The Farkas Center for Light Induced Processes, The Hebrew University of Jerusalem, 91904, Jerusalem, Israel

Publisher

American Chemical Society (ACS)

Subject

Spectroscopy,Structural Biology

Link

https://pubs.acs.org/doi/pdf/10.1016/S1044-0305%2899%2900042-2

Reference36 articles.

1. Theory and experiment in concert: the [MeOC:O]+ ion and its isomers

2. Methyl cation affinities

3. G2 Theory and Experiment in Concert: Enthalpy of Formation of CH3O−CO+ and Its Isomers Revisited

4. Cyclization of dimethyl oxalate upon electron impact

5. Mass spectrometric approaches to the reactivity of transient neutrals

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1. Dissociative Photoionization of Dimethyl Carbonate: The More It Is Cut, the Bigger the Fragment Ion;The Journal of Physical Chemistry A;2017-03-30

2. Interplay of thermochemistry and Structural Chemistry, the journal (volume 16, 2005) and the discipline;Structural Chemistry;2010-01-23

3. Unimolecular chemistry of metastable dimethyl isophthalate radical cations;International Journal of Mass Spectrometry;2008-08

4. Decarbonylation of two α-diketones: 1,2-Bis(6-methylpyridin-2-yl)ethane-1,2-dione and 1-(pyridin-2-yl)-2-(6-methylpyridin-2-yl)ethane-1,2-dione;International Journal of Mass Spectrometry;2007-04

5. The Kinetic Method as a Structural Diagnostic Tool: Ionized α-Diketones as Loosely One-Electron Bonded Diacylium Ion Dimers;European Journal of Mass Spectrometry;2003-08

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