Claisen Rearrangements in Nitrogen Heterocyclic Systems

Author:

Thyagarajan B.S.

Publisher

Elsevier

Reference31 articles.

1. The stereospecific total synthesis of d1-8β-carbomethoxy-13-oxopodocarpane, a degradation product of phyllocladene

2. “The Chemistry of Heterocyclic Compounds,”;Klingsberg,1962

3. In a paper4 that has often been overlooked as a contribution to the study of Claisen rearrangement of pyridyl and quinolyl allyl ethers (largely because it emphasized in its title the synthesis of antimalarial compounds) the allyl ethers were obtained by reacting hydroxyquinolines and hydroxypyridines with allyl bromide in acetone in the presence of potassium carbonate as base. None of the products from such a reaction was examined to verify if they were N-allyl or O-allyl derivatives. These were then subjected to rearrangement in refluxing alpha methylnaphthalene and the products of rearrangement were assumed to be the corresponding C-allylhydroxypyridines and quinolines.

4. Über einen neuen, gegen Vogelmalaria wirksamen Verbindungstypus

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1. Formation of Alcohols and Phenols by Ether Cleavage;Comprehensive Organic Transformations;2018-02-28

2. References;Chemistry of Heterocyclic Compounds: A Series Of Monographs;2008-01-02

3. References;Chemistry of Heterocyclic Compounds: A Series Of Monographs;2008-01-02

4. Lewis acid catalyzed Claisen rearrangement: Regioselective synthesis of oxygen, nitrogen, and sulfur heterocycles;Canadian Journal of Chemistry;2008-01-01

5. Regioselective synthesis of 7-acetyl-11c-methyl-4b,5,7,11c-tetrahydro[1]benzofuro[2′,3′:4,5]thiopyrano[2,3-b]indoles by sequential Claisen rearrangement of 2-(4′-aryloxybut-2′-ynylthio)-1-acetylindoles;Journal of Chemical Research;2006-05

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