The subtle electronic effects of alkyl groups on the conformational equilibria and intramolecular hydrogen-bond strength in cis-3-alkoxycyclohexanols
Author:
Publisher
Elsevier BV
Subject
Spectroscopy,Instrumentation,Atomic and Molecular Physics, and Optics,Analytical Chemistry
Reference25 articles.
1. Conformer dipole moment and syn-1,3-diaxial steric effect on the conformational equilibrium of the cis isomer of some 1,3-disubstituted cyclohexanes
2. The relevant effect of an intramolecular hydrogen bond on the conformational equilibrium of cis-3-methoxycyclohexanol compared to trans-3-methoxycyclohexanol and cis-1,3-dimethoxycyclohexane
3. Influence of intramolecular hydrogen bonding on the conformational equilibrium ofcis-3-N,N-dimethylaminocyclohexanol compared withtrans-3-N,N-dimethylaminocyclohexanol andcis- andtrans-3-N,N-dimethylamino-1-methoxycyclohexane
4. The anomeric effect in substituted cyclohexanes. I. The role of hyperconjugative interactions and steric effect in monosubstituted cyclohexanes
5. Hyperconjugation and the Increasing Bulk of OCOCX3 Substituents in Trans-1,4-Disubstituted Cyclohexanes Destabilize the Diequatorial Conformer
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1. Dealing with Hydrogen Bonding on the Conformational Preference of 1,3-Aminopropanols: Experimental and Molecular Dynamics Approaches;The Journal of Physical Chemistry A;2019-09-13
2. Strong hyperconjugative interactions limit solvent and substituent influence on conformational equilibrium: the case of cis-2-halocyclohexylamines;Beilstein Journal of Organic Chemistry;2019-04-01
3. DFT calculations and NMR measurements applied to the conformational analysis of cis and trans -3-phenylaminocyclohexyl N,N -dimethylcarbamates;Journal of Molecular Structure;2018-07
4. Alkyl Group Effect on the Conformational Isomerism of trans-2-Bromoalkoxycyclohexanes Analyzed by NMR Spectroscopy and Theoretical Calculations;The Journal of Physical Chemistry A;2011-08-05
5. Influence of OH⋯N and NH⋯O inter- and intramolecular hydrogen bonds in the conformational equilibrium of some 1,3-disubstituted cyclohexanes through NMR spectroscopy and theoretical calculations;Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy;2011-05
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