Palladium- and base-free synthesis of conjugated ynones by cross-coupling reactions of alkynylboronates with acid chlorides mediated by CuCl
Author:
Publisher
Elsevier BV
Subject
Organic Chemistry,Drug Discovery,Biochemistry
Reference79 articles.
1. A simple synthesis of dienones via isomerization of alkynones effected by palladium catalysts
2. Synthesis of Ynones by Palladium-Catalyzed Acylation of Terminal Alkynes with Acid Chlorides
3. Preparation of α,β-acetylenic ketones by catalytic heterogeneous oxidation of alkynesElectronic Supplementary information (ESI) available: details of the synthesis and characterisation of authentic ynones; kinetic curves of the oct-4-yne oxidation under air and under argon; mass spectra of oct-4-yn-3-one and 4-phenylbut-3-yn-2-one obtained in labelling studies; DR UV-vis spectra of catalyst 2 before and after 3 successive oxidations. See http://www.rsc.org/suppdata/cc/b2/b204122g/
4. Synthesis of novel C-nucleosides with potential applications in combinatorial and parallel synthesis
5. Structure–activity relationship of neuritogenic spongean acetylene alcohols, lembehynes
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