Enantioselective formal total synthesis of the Dendrobatidae frog toxin, (+)-pumiliotoxin B, via O-directed alkyne free radical hydrostannation
Author:
Publisher
Elsevier BV
Subject
Organic Chemistry,Drug Discovery,Biochemistry
Reference26 articles.
1. O-Directed Free-Radical Hydrostannations of Propargyl Ethers, Acetals, and Alcohols with Ph3SnH and Et3B
2. On the Stereospecific Conversion of Proximally-Oxygenated Trisubstituted Vinyltriphenylstannanes into Stereodefined Trisubstituted Alkenes
3. Mechanistic Studies on the O-Directed Free-Radical Hydrostannation of Disubstituted Acetylenes with Ph3SnH and Et3B and on the Iodination of Allylically Oxygenated α-Triphenylstannylalkenes
4. Total synthesis of (+)-A83586C, (+)-kettapeptin and (+)-azinothricin: powerful new inhibitors of β-catenin/TCF4- and E2F-mediated gene transcription
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2. EPR evidence for α-triphenylstannylvinyl radicals in the O-directed hydrostannation of dialkylacetylenes with Ph3SnH/cat. Et3B/O2;Chemical Communications;2021
3. The stannylvinyl cation that never was! New concentration- and temperature-dependent probe studies confirm an entirely free radical mechanism and O–Sn coordinative control of the hydrostannation of propargylically-oxygenated dialkyl acetylenes with stannanes and cat. Et3B;Tetrahedron;2020-05
4. Twofold π-Extension of Polyarenes via Double and Triple Radical Alkyne peri-Annulations: Radical Cascades Converging on the Same Aromatic Core;Journal of the American Chemical Society;2020-04-04
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