Reversible nucleophilic addition can lower the observed enantioselectivity in palladium-catalyzed allylic amination reactions with a variety of chiral ligands-Reference-Cited by-同舟云学术

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Reversible nucleophilic addition can lower the observed enantioselectivity in palladium-catalyzed allylic amination reactions with a variety of chiral ligands

Published:2015-09 Issue:40 Volume:56 Page:5445-5448
ISSN:0040-4039
Container-title:Tetrahedron Letters
language:en
Short-container-title:Tetrahedron Letters

Author:

Caminiti Nicholas S.,Goodstein Madison B.,Leibler Isabelle N.-M.,Holtzman Bryan S.,Jia Zitong B.,Martini Michael L.,Nelson Nathaniel C.,Bunt Richard C.

Funder

Donors of The Petroleum Research Fund

American Chemical Society, and the National Science Foundation

Middlebury College

Publisher

Elsevier BV

Subject

Organic Chemistry,Drug Discovery,Biochemistry

Reference55 articles.

1. Transition Metal Catalyzed Enantioselective Allylic Substitution in Organic Synthesis,2012

2. Catalytic asymmetric allylic alkylation employing heteroatom nucleophiles: a powerful method for C–X bond formation

3. Regioselectivity in the Palladium/(S)-BINAP(S)-Catalyzed Asymmetric Allylic Amination: Reaction Scope, Kinetics, and Stereodynamics

4. Asymmetric Transition-Metal-Catalyzed Allylic Alkylations: Applications in Total Synthesis

5. Allylic Amination

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1. Insight into Stereocontrol in the Asymmetric Intramolecular Allylation with a tert-Butylsulfinamide Nucleophile: Application in the Synthesis of Chiral Isoindoline-1-Carboxylic Acid Esters;J ORG CHEM;2023

2. Synthesis of Amines and Ammonium Salts;Reference Module in Chemistry, Molecular Sciences and Chemical Engineering;2023

3. Insight into Stereocontrol in the Asymmetric Intramolecular Allylation with a tert-Butylsulfinamide Nucleophile: Application in the Synthesis of Chiral Isoindoline-1-Carboxylic Acid Esters;The Journal of Organic Chemistry;2022-12-22

4. Asymmetric intermolecular allylic C–H amination of alkenes with aliphatic amines;Science;2022-12-16

5. Kinetics and Mechanisms of the Gold-Catalyzed Hydroamination of Axially Chiral 1-Aryl-1,2-butadienes with Aniline;Organometallics;2022-09-19

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