Controlled endocyclic and exocyclic γ-metalations of β-substituted cyclohexenyl sulfones. Regiospecific syntheses of γ-oxygenated cyclohexenyl sulfones.-Reference-Cited by-同舟云学术

Controlled endocyclic and exocyclic γ-metalations of β-substituted cyclohexenyl sulfones. Regiospecific syntheses of γ-oxygenated cyclohexenyl sulfones.

Published:1991-06 Issue:25 Volume:32 Page:2861-2864
ISSN:0040-4039
Container-title:Tetrahedron Letters
language:en
Short-container-title:Tetrahedron Letters

Author:

Lee S.W,Fuchs P.L

Publisher

Elsevier BV

Subject

Organic Chemistry,Drug Discovery,Biochemistry

Reference10 articles.

1. A versatile and expedient synthesis of .alpha.,.beta.-unsaturated ketones. Utilization of the .beta.-epoxy sulfone functional group as the enone progenitor

2. Conjugate-addition reactions of organometallic reagents to γ-oxygenated-α,β-unsaturated sulfones: Control of stereochemistry at the β-position

3. Conjugate-addition reactions of highly-functionalized aryl lithium reagents to γ-silyloxy-α,β-unsaturated sulfones: consequences of the structure of the sulfone moiety.

4. Multiply convergent syntheses via conjugate-addition reactions to cycloalkenyl sulfones

5. A triply convergent total synthesis of l(-)-prostaglandin E2

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