Kinetics and spectroscopy of ylids from reaction of p-substituted phenylchlorocarbenes with acetone

Author:

Soundararajan N,Jackson James E,Platz Matthew S,Liu Michael T.H

Publisher

Elsevier BV

Subject

Organic Chemistry,Drug Discovery,Biochemistry

Reference7 articles.

1. N. Soundararajan, M.S. Platz, J.E. Jackson, M.P. Doyle, S.-M. Oon, M.T.H. Liu, and S.M. Anand Submitted for publication in J. Am. Chem. Soc..

2. Fluorenylidene;Wong;J. Am. Chem. Soc.,1982

3. Naphthyl carbene;Barcus;J. Am. Chem. Soc.,1986

4. N. Soundararajan, J.E. Jackson, M.S. Platz, unpublished observations. We estimate an upper bound for the carbene-acetone rate constant of ~2 × 104 M−1s−1, limited by dimerization and reaction with diazirine precursor.

5. Kinetic studies of chloro-p-nitrophenylcarbene with acetone and diethyl fumarate

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