Structure and reactivity of Cp2Zr(η2-Me2SiNtBu)(CO): An unusual silanimine carbonyl complex with extensive σ-π∗ back-bonding
Author:
Publisher
Elsevier BV
Subject
Materials Chemistry,Inorganic Chemistry,Physical and Theoretical Chemistry
Reference74 articles.
1. .eta.2-Silanimine complexes of zirconocene: synthesis, structure, and reactivity of Cp2Zr(.eta.2-SiMe2:N-tert-Bu)(PMe3)
2. Reactions of carbon dioxide and carbon disulfide with .eta.2-silanimine complexes of zirconium: facile deoxygenation and desulfurization reactions
3. Insertion of carbon monoxide into a transition metal-silicon bond. X-ray structure of the silaacyl chloro(trimethylsilyl-.eta.2-carbonyl)bis(.eta.5-cyclopentadienyl)zirconium
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