The crystal structure of a novel complex [Sm(HMPA)3(H20)4]3+3[I−] formed in the reductive cyclodimerization of linear α,β-unsaturated ketones by SmI2-Reference-Cited by-同舟云学术

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The crystal structure of a novel complex [Sm(HMPA)3(H20)4]3+3[I−] formed in the reductive cyclodimerization of linear α,β-unsaturated ketones by SmI2

Published:1996-06 Issue:17 Volume:15 Page:2971-2973
ISSN:0277-5387
Container-title:Polyhedron
language:en
Short-container-title:Polyhedron

Author:

Cabrera Armando,Rosas Noé,Alvarez Cecilio,Sharma Pankaj,Toscano Alfredo,Salmon Manuel,Arias Jose Luis

Publisher

Elsevier BV

Subject

Materials Chemistry,Inorganic Chemistry,Physical and Theoretical Chemistry

Reference9 articles.

1. A novel cyclodimerization of α,β-unsaturated carbonyl compounds promoted by ytterbium metal

2. A facile reductive dimerization of conjugated acid derivatives with samarium diiodide

3. Samarium(II) iodide - HMPA: A very efficient system for the selective reduction of α,β,-unsaturated carbonyl compounds

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3. Scandium, Yttrium, and the Lanthanides;Comprehensive Coordination Chemistry II;2003

4. Samarium(II)-Mediated Reactions of γ,δ-Unsaturated Ketones. Cyclization and Fragmentation Processes;Organic Letters;2002-06-19

5. Samarium diiodide-promoted sequential coupling-aldol-reduction reactions of ferrocene-substituted enones;Comptes Rendus de l'Académie des Sciences - Series IIC - Chemistry;2001-06

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