Reactions of the polyhydride complex ReH7(dppe) (dppe = Ph2PCH2CH2PPh2) with pyridine-2-carboxylic acid, 1-isoquinolinecarboxylic acid, 2-hydroxy-6-methylpyridine and 2-mercaptoquinoline. synthesis and structural characterization of seven-coordinate monohydrido complexes of rhenium(iii)
Author:
Publisher
Elsevier BV
Subject
Materials Chemistry,Inorganic Chemistry,Physical and Theoretical Chemistry
Reference17 articles.
1. Reactions of the polyhydride complex ReH7(PPh3)2 with pyridinecarboxylic acids, 2-hydroxypyridine, 2-hydroxy-6-methylpyridine, and acetylacetone. Monohydrido complexes of rhenium(III) and their oxidation to the corresponding rhenium(IV) derivatives
2. Reactions of the polyhydride complex ReH7(PPh3)2 with hydroxypyridine and mercaptopyridine ligands. Formation of hydrido complexes of rhenium(III), rhenium(IV), and rhenium(V) and the characterization of eight-coordinate isomers in the solid state and in solution
3. Reactions of the polyhydride complex ReH7(PPh3)2 with quinoline, 2-hydroxyquinoline, and 2-mercaptoquinoline. The preparation and characterization of hydrido complexes of rhenium(V) and chloro complexes of rhenium(III)
4. Activation of alkynes by rhenium polyhydrides in the presence of electrophiles: facile formation of hydrido-alkylidyne complexes
5. Reactions of Rhenium Polyhydrides with Internal and Terminal Alkynes as a Route to a New Class of Hydrido-Alkylidyne Complexes
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1. Ortho-metalation, rotational isomerization, and hydride–hydride coupling at rhenium (V) polyhydride complexes stabilized by aromatic amine ligands;Inorganica Chimica Acta;2009-07
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