Conjugate addition of (trimethylstannyl)copper reagents to α,β-acetylenic N,N-dimethylamides. Trapping of the intermediates with electrophiles
Author:
Publisher
Elsevier BV
Subject
Organic Chemistry,Drug Discovery,Biochemistry
Reference10 articles.
1. Stereoselective conjugate addition of lithium (phenylthio)(trimethylstannyl) cuprate to .alpha.,.beta.-acetylenic esters. Preparation of (E)- and (Z)-4-lithio-1,3-pentadienes and their reaction with electrophiles
2. Reaction of (trimethylstannyl) copper reagents with α, β-acetylenic esters
3. Two unprecedented observations in organocuprate chemistry: reversibility of addition to an alkyne and low pKa of a stannylcuprate
4. Synthesis and transmetalation of alkyl (E)-2,3-bis(trimethylstannyl)-2-alkenoates, novel organotin compounds
5. Chemistry of substituted (.alpha.-carbethoxyvinyl)cuprates. 2. Stereospecific olefin synthesis
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