Duality of mechanism in the addition of allylic grignard reagents to carbon-carbon double bonds. The stereoselective cyclisation of 2,7-octadienylmagnesium bromide to -(2-vinylcyclopentyl)-methylmagnesium bromide-Reference-Cited by-同舟云学术

Duality of mechanism in the addition of allylic grignard reagents to carbon-carbon double bonds. The stereoselective cyclisation of 2,7-octadienylmagnesium bromide to -(2-vinylcyclopentyl)-methylmagnesium bromide

Published:1972-01 Issue:22 Volume:13 Page:2285-2288
ISSN:0040-4039
Container-title:Tetrahedron Letters
language:en
Short-container-title:Tetrahedron Letters

Author:

Felkin Hugh,David Umpleby J.,Hagaman Edward,Wenkert Ernest

Publisher

Elsevier BV

Subject

Organic Chemistry,Drug Discovery,Biochemistry

Reference17 articles.

1. Facile Addition of a Grignard Reagent to an Unconjugated Ethylenic Linkage

2. Addition of grignard reagents to the double bond of allylic alcohols

3. Promotion by primary and tertiary amine functions of additions of grignard reagents to alkenes and alkynes

4. Addition of organolithium reagents to the double bond of allylic alcohols

5. Kinetics and mechanism of the addition of allyl magnesium bromide to the double bond of cinnamyl alcohol. Catalysis by magnesium bromide.

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