A novel one-flask cyclopentannulation involving a dilithiomethane equivalent as a β-connector of two enones. A highly efficient total synthesis of (±)-hirsutene-Reference-Cited by-同舟云学术

A novel one-flask cyclopentannulation involving a dilithiomethane equivalent as a β-connector of two enones. A highly efficient total synthesis of (±)-hirsutene

Published:1993-09 Issue:36 Volume:49 Page:7931-7942
ISSN:0040-4020
Container-title:Tetrahedron
language:en
Short-container-title:Tetrahedron

Author:

Cohen Theodore,McNamara Kevin,Kuzemko Michael A.,Ramig Keith,Landi John J.,Dong Yong

Publisher

Elsevier BV

Subject

Organic Chemistry,Drug Discovery,Biochemistry

Reference44 articles.

1. 1,3-Elimination reactions of (3,4-epoxybutyl)stannanes. Approach to the synthesis of cycloeudesmol

2. A general approach to linearly fused triquinane natural products. Total syntheses of (.+-.)-hirsutene, (.+-.)-coriolin, and (.+-.)-capnellene

3. Use of dilithiomethane equivalent in a novel one-flask [2 + 1 + 2] cyclopentannulation reaction: a highly efficient total synthesis of (.+-.)-hirsutene.

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