Conversion of α,β-unsaturated ketones into α-hydroxy ketones using an MnIII catalyst, phenylsilane and dioxygen: acceleration of conjugate hydride reduction by dioxygen

Author:

Magnus Philip,Payne Andrew H,Waring Michael J,Scott David A,Lynch Vince

Funder

Welch Foundation

Merck

National Institutes of Health

Publisher

Elsevier BV

Subject

Organic Chemistry,Drug Discovery,Biochemistry

Reference26 articles.

1. Synthesis of the Kopsia alkaloids (±)-11,12-demethoxylahadinine B, (±)-kopsidasine and (±)-kopsidasine-N-oxide

2. Inoki, S.; Kato, K.; Isayama, S.; Mukaiyama, T. Chem. Lett. 1990, 1869. For a review see: Mukaiyama, T. Oxygenation of olefins with molecular oxygen catalyzed by low valent metal complexes. The activation of dioxygen and homogeneous catalytic oxidation; Barton, D. H. R.; Martell, A. E.; Sawyer, D. T., Ed.; Plenum Press: New York, 1993.

3. Fernelius, W. C.; Bryant, B. E. Inorg. Synth. 1957, 5, 105. Fackler Jr., J. P. Prog. Inorg. Chem. 1966, 7, 361. Higher oxidation states of manganese: Levason, W.; McAuliffe, C. A. Coord. Chem. Rev. 1972, 7, 353.

4. Chelates of β-Diketones. I. Enolization, Ionization and Spectra

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