Strategy for contra-thermodynamic radical-chain epimerisation of 1,2-diols using polarity-reversal catalysis
Author:
Publisher
Elsevier BV
Subject
Organic Chemistry,Drug Discovery,Biochemistry
Reference22 articles.
1. Selective radical-chain epimerisation at CH centres α to oxygen under conditions of polarity-reversal catalysis
2. Beitr�ge zur Chemie der Silicium-Schwefel-Verbindungen. XXIII. Die Hydrolysereaktion der Silanthiole
3. The role of the collidine (2,4,6-trimethylpyridine) is probably to act as a scavenger of acid resulting from reactions between the initiator and the thiol.1
4. Polarity-reversal catalysis of hydrogen-atom abstraction reactions: concepts and applications in organic chemistry
5. Calculations were carried out using pcmodel version 7 (Serena Software, Bloomington, Indiana 47402-3076, USA); differences in MMX energies are reported.
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