Enantioselective syntheses of (+)-α-skytanthine, (+)-δ-skytanthine and (+)-iridomyrmecin by an intramolecular magnesium-ene reaction.
Author:
Publisher
Elsevier BV
Subject
Organic Chemistry,Drug Discovery,Biochemistry
Reference36 articles.
1. Intramolecular type-II "metallo-ene" reactions of (2-alkenylallyl)magnesium chlorides: regio- and stereochemical studies
2. Short and selective total synthesis of (.+-.)-khusimone via an intramolecular type II "magnesium-ene" reaction
3. Total synthesis of (±)-Δ9(12)-capnellene via iterative intramolecular type-I-“Magnesium-ene” reactions
4. Stereoselective total syntheses of (±)-sinularene and of (±)-5-epi-sinularene via intramolecular type-I-“magnesium-ene” reaction
5. Application of the intramolecular magnesium-ene reaction to the stereocontrolled total syntheses of (±)-12-acetoxysinularene and (±)-5-epi-12-acetoxysinularene
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