Diastereoselectivity in non-aldol aldol reactions: silyl triflate-promoted Payne rearrangements
Author:
Publisher
Elsevier BV
Subject
Organic Chemistry,Drug Discovery,Biochemistry
Reference19 articles.
1. Enantiospecific synthesis of all four diastereomers of 2-methyl-3-[(trialkylsilyl)oxy]alkanals: facile preparation of aldols by non-aldol chemistry
2. Stereospecific Formation of Optically Active 5-Alkyl-4-methyl-3-[(trialkylsilyl)oxy]-2-([(trialkylsilyl)oxy]- methyl)tetrahydrofurans via Diastereoselective Epoxidation and Rearrangement of 5-[(Trialkylsilyl)oxy]-2-alken-1-ols1
3. Conversion of Homoallylic Alcohols with Alkene Protection to the Corresponding Methyl Ketones
4. Rearrangement of epoxides in non-aldol aldol process: Allylic vs. Tertiary and secondary carbocationic centers
5. Synthesis of Four Diastereomeric 3,5-Dialkoxy-2,4-dimethylalkanals by a Simple Extension of the Non-Aldol Aldol Process to Bis(propionates)
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1. Preparation of β-hydroxyketones (aldols) from the alkylation of O-silyl aryl cyanohydrins with epoxides;Tetrahedron Letters;2023-02
2. The Semipinacol Rearrangements;Reference Module in Chemistry, Molecular Sciences and Chemical Engineering;2023
3. Trapping of Payne rearrangement intermediates with arylselenide anions;Tetrahedron Letters;2015-06
4. 3.16 The Semipinacol Rearrangements;Comprehensive Organic Synthesis II;2014
5. Tandem Payne/Meinwald versus Meinwald rearrangements on the α-hydroxy- or α-silyloxy-spiro epoxide skeleton;Org. Biomol. Chem.;2012
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