On the configuration of open chain α-sulfonyl carbonions: X-ray crystal structure of [(phenylsulfonyl)isopropyllithium-diglyme]2 and [(α-phenylsulfonyl)-α-(methyl)benzyllithium-diglyme]2-Reference-Cited by-同舟云学术

On the configuration of open chain α-sulfonyl carbonions: X-ray crystal structure of [(phenylsulfonyl)isopropyllithium-diglyme]2 and [(α-phenylsulfonyl)-α-(methyl)benzyllithium-diglyme]2

Published:1988-01 Issue:11 Volume:29 Page:1259-1262
ISSN:0040-4039
Container-title:Tetrahedron Letters
language:en
Short-container-title:Tetrahedron Letters

Author:

Gais Hans-Joachim,Vollhardt Jürgen,Hellmann Gunther,Paulus Helmut,Lindner Hans J.

Publisher

Elsevier BV

Subject

Organic Chemistry,Drug Discovery,Biochemistry

Reference12 articles.

1. Electrophilic substitution at saturated carbon. XLV. Dissection of mechanisms of base-catalyzed hydrogen-deuterium exchange of carbon acids into inversion, isoinversion, and racemization pathways

2. The stereochemical course of protonation of α-sulfonyl carbanions

3. Acidities of sulfoximines and related oxosulfonium cations. Cyclopropyl effects and structures of .alpha.-sulfonyl-type carbanions

4. Stabilization of carbanions by polarization of alkyl groups on nonadjacent atoms

5. Structure of sulfur-stabilized carbanions. A 13C NMR study of some α-lithio-sulfoxides and sulfones

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