Rates in the solvolysis of 2-octyl methanesulfonate in 30% aqueous dioxane in the presence of sodium azide and the question of borderline behavior
Author:
Publisher
Elsevier BV
Subject
Organic Chemistry,Drug Discovery,Biochemistry
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1. Substitution at a saturated carbon atom. X. Unification of mechanisms Snl and Sn2
2. Substitution at a saturated carbon atom. XVII. Organic ion pairs as intermediates in nucleophilic substitution and elimination reactions
3. Evidence for a unifying mechanism of nucleophilic substitution into sulfonium ions
4. Further unusual deuterium isotope effects—βversusα—on the polarimetric rate of solvolysis of threo-1-methyl-2-phenylpropyl toluene-p-sulphonate and the question of non-classical carbonium ion intermediates
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1. Dissection of isotope effects. IV. Dissected deuterium effects in the solvolysis of 2-octyl-3,3-2 brosylate in 65% aqueous ethanol and the question of the temperature dependence of -deuterium effects;Tetrahedron Letters;1978-01
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