The preparation and reactions of lithio -butyl(trimethylsilyl) acetate. A synthesis of α-silylated vinyl esters.
Author:
Publisher
Elsevier BV
Subject
Organic Chemistry,Drug Discovery,Biochemistry
Reference5 articles.
1. Reaction of lithio -butyl trimethylsilylacetate with aldehydes and ketones. A synthesis of α,β-unsaturated esters.
2. New synthesis of .alpha.,.beta.-unsaturated carboxylic esters
3. O-Silylation and Attempted O-Alkylation of Lithium Ester Enolates. The Synthesis of O-Silyl Ketene Acetals
4. Regiospecific Michael reactions in aprotic solvents with .alpha.-silylated electrophilic olefins. Application to annelation reactions
5. Regiospecificity in enolate reactions with .alpha.-silyl vinyl ketones. Application to steroid total synthesis
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1. Diastereoselective Syntheses of (E)-α-Trialkylsilyl α,β-Unsaturated Esters, α-Silane-Substituted Conjugated Silyl Ketene Acetals, and α,γ-Substituted Allylsilanes;The Journal of Organic Chemistry;2018-07-25
2. Vicinal Functionalization of Propiolate Esters via Catalytic Carbocupration: Stereoselective Formation of Substituted Vinyl Silanes;Organic Letters;2010-05-13
3. Ethyl Lithio(trimethylsilyl)acetate;Encyclopedia of Reagents for Organic Synthesis;2010-03-15
4. A Highly Stereoselective TMSOTf-Mediated Catalytic Carbocupration of Alkynoates;Organic Letters;2007-11-15
5. t-Butyl bis(trimethylsilyl)lithioacetate;Fieser and Fieser's Reagents for Organic Synthesis;2006-12-15
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