Preparation of 2-lithiotetrahydropyrans: Kinetic and thermodynamic generation of alkyllithium reagents
Author:
Publisher
Elsevier BV
Subject
Organic Chemistry,Drug Discovery,Biochemistry
Reference19 articles.
1. Two-flask preparation of .alpha.-lithio cyclic ethers from .gamma.- and .delta.-lactones. Reductive lithiation as a route, via radical intermediates, to axial 2-lithiotetrahydropyrans and their equilibration to the equatorial isomers
2. A general preparative method for .alpha.-lithioethers and its application to a concise, practical synthesis of brevicomin
3. Hydrolithiation of .alpha.-olefins by a regiospecific two-step process. Transformation of alkyl phenyl sulfides to alkyllithium reagents
4. Markownikoff two-step hydrolithiation of .alpha.-olefins. Transformation of secondary and tertiary alkyl phenyl sulfides to the relevant alkyllithium reagents
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