Synthesis of oxacyclic carboxylic esters by way of methoxycarbonyloxonium ions; Evidence for a cationic oxa-cope rearrangement
Author:
Publisher
Elsevier BV
Subject
Organic Chemistry,Drug Discovery,Biochemistry
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1. Reaction of 2-methoxyethyl acetals with allylsilanes in the presence of titanium tetrachloride: regioselective carbon-oxygen bond cleavage of the unsymmetrical acetals
2. Diastereoselective Synthesis of 2,3-cis-Alkyl-3-oxygenated Piperidine Derivatives by Titanium Mediated Intramolecular Cyclization of a-Aminoacetal-allylsilane System
3. Acetal-initiated cyclization of allylsilanes to highly functionalized piperidine derivatives
4. Synthesis of 4-halotetrahydropyrans from allylsilanes and carbonyl compounds in the presence of lewis acids
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