Chiral organometallic NADH mimics: Preparation of homochiral (R)-(−)[(η5-c5h5)fe(co)(pph2(o-(l)-menthyl1))]-1-methyl-1,4-dihydronicotinand asymmetric reduction of ethyl benzoylformate.
Author:
Publisher
Elsevier BV
Subject
Organic Chemistry,Drug Discovery,Biochemistry
Reference18 articles.
1. Mechanistic models of asymmetric reductions;Ohno,1986
2. Model studies with nicotinamide derivatives
3. Reduction by a model of NAD(P)H. Effect of metal ion and stereochemistry on the reduction of .alpha.-keto esters by 1,4-dihydronicotinamide derivatives
4. Reduction by a model of NAD(P)H. 25. A chiral model which induces high asymmetry
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