Asymmetric aldol reactions. Mechanism of solvent effect on stereoselectivity is specific, stoichiometric binding of tetrahydrofuran to a chiral titanium enolate-Reference-Cited by-同舟云学术

Asymmetric aldol reactions. Mechanism of solvent effect on stereoselectivity is specific, stoichiometric binding of tetrahydrofuran to a chiral titanium enolate

Published:1990-01 Issue:33 Volume:31 Page:4699-4702
ISSN:0040-4039
Container-title:Tetrahedron Letters
language:en
Short-container-title:Tetrahedron Letters

Author:

Shirodkar Shailaja,Nerz-Stormes Maryellen,Thornton Edward R.

Publisher

Elsevier BV

Subject

Organic Chemistry,Drug Discovery,Biochemistry

Reference11 articles.

1. Very high diastereofacial selectivities in convenient titanium—mediated aldol reactions

2. Apparent chelation control in aldol reactions of chiral (Me2CHO)3Ti-enolates

3. Asymmetric aldol reactions. A titanium enolate giving very high diastereofacial selectivities

4. The value of 31:1 is higher than that given previously,2 as a result of additonal experiments: Nerz-Stormes, M.; Thornton, E. R., to be published.

5. Enantioselective aldol condensations. 2. Erythro-selective chiral aldol condensations via boron enolates

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