)-(+)-2-(-tolylsulfinyl)-2-buten-4-olide: an enantiomerically pure Michael acceptor for asymmetric synthesis of 3-substituted 4-butanolides. (

)-(+)-2-(-tolylsulfinyl)-2-buten-4-olide: an enantiomerically pure Michael acceptor for asymmetric synthesis of 3-substituted 4-butanolides. (—)-podorhizon.

Published:1984-01 Issue:25 Volume:25 Page:2627-2630
ISSN:0040-4039
Container-title:Tetrahedron Letters
language:en
Short-container-title:Tetrahedron Letters

Author:

Posner Gary H.,Kogan Timothy P.,Haines Stephen R.,Frye Leah L.

Publisher

Elsevier BV

Subject

Organic Chemistry,Drug Discovery,Biochemistry

Reference34 articles.

1. High asymmetric induction during organometallic .beta.-addition to .alpha.,.beta.-ethylenic sulfoxides. Synthesis of optically active .beta.-alkylcarboxylic acids, .beta.-substituted cyclopentanones, and steroidal 11-oxoequilenin methyl ether

2. Complete asymmetric induction in synthesis of enantiomerically pure steroid intermediates of natural configuration

3. Asymmetric induction during organometallic conjugate addition to enantiomerically pure 2-(arylsulfinyl)-2-cyclopentenones

4. Enantiocontrolled synthesis of ()-3-substituted cycloalkanones from ()-2-(-tolylsulfinyl)-2-cycloalkenones and diorganomagnesium reagents.

5. Enantiocontrolled synthesis of quaternary carbon centers. 3,3-Disubstituted cyclopentanones. (+)-α-cuparenone.

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